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Electrocatalytic reduction of CO2 to CO by Gd(III) and Dy(III) complexes; and M2O3 nanoparticles (M = Gd and Dy)


Two Gd(III) and Dy(III) complexes, [M(AyGG)3(H2O)5] (AyGG = Alizarin yellow GG (NaC13H8N3O5)), have been prepared and characterized. The Gd2O3 and Dy2O3nanoparticles were prepared by the calcination of the Gd(III) and Dy(III) complexes in air at different temperatures. The nanoparticles were characterized by FT-IR, X-ray diffraction analysis (XRD), and field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The voltammograms in the absence and presence of CO2 indicate that the Gd(III) and Dy(III) complexes and their nano-oxides can catalyze the electrochemical reduction of CO2 to CO. The results show that the Dy(III) complex has better electrocatalytic activity than other compounds.

Journal Papers